Chapter 4: Structure of the Atom

4.1 Charged Particles in Matter

An atom is divisible and consists of charged particles. Key sub-atomic particles:

  • Electron (e⁻): Discovered by J.J. Thomson. Negligible mass, charge -1.
  • Proton (p⁺): Discovered by E. Goldstein (Canal Rays). Unit mass, charge +1.
  • Neutron (n): Discovered by J. Chadwick. Unit mass, no charge.

4.2 Atomic Models

Thomson's Model

Similar to a "Christmas Pudding" or "Watermelon". Positive charge is spread all over, and electrons are embedded like seeds.

Rutherford's Model

Nuclear model based on the alpha-particle scattering experiment. Identified the Nucleus as a tiny, dense, positively charged center.

Bohr's Model

Electrons revolve in discrete orbits called energy levels (K, L, M, N). They do not radiate energy while in these orbits.

4.3 Electron Distribution

Bohr-Bury Scheme: Maximum electrons in a shell = 2n².

  • K shell (n=1) → 2 electrons
  • L shell (n=2) → 8 electrons
  • M shell (n=3) → 18 electrons

4.4 Valency

The combining capacity of an atom is called valency. Atoms react to achieve an octet in their outermost shell.

4.6 Isotopes and Isobars

Isotopes: Atoms of same element with same atomic number but different mass numbers (e.g., Protium, Deuterium, Tritium).

Isobars: Atoms of different elements with same mass number but different atomic numbers (e.g., Calcium and Argon both have mass 40).

Properties Table

ParticleMass (u)ChargeLocation
Proton1+1Nucleus
Neutron10Nucleus
Electron1/2000 approx-1Orbits